Biphasic Catalytic(Hydroformylation of 1-Dodecene in Micellar System with Cationic Gemini Surfactants
The promotion effect of cationic gemini surfactants for the hydroformylation of 1-dodecene in the organic/aqueous biphasic catalytic system is reported. The hydroformylation reaction in the presence of gemini surfactant occurred with higher turnover frequency and higher selectivity for linear aldehyde than using conventional monomeric surfactant CTAB.
作 者： Min Li Bin XU Hua CHEN Hong Jie ZHENG Xue Yuan HUANG Yao Zhong LI Xian Jun LI 作者单位： Department of Chemistry,Sichuan University,Chengdu 610064 刊 名： 中国化学快报(英文版) ISTIC SCI 英文刊名： CHINESE CHEMICAL LETTERS 年，卷(期)： 2004 15(9) 分类号： 关键词： Hydroformylation gemini surfactant 1-dodecene rhodium catalyst