Dehydration of Oximes to Nitriles Catalyzed by a Green Heteropolyacid Catalyst :Preysslers Anion,[NaP5W30O110]14-
A mild, simple and high yielding procedure for the direct conversion of oximes to nitriles has been developed using heteropolyacid in acetic acid. Aromatic and aliphatic aldoximes wee converted to the corresponding nitriles in the presence of Preyssler type heteropolyacid. Which could be reused several times without any appreciable loss of activity
作 者: HERAVI,Majid M. SADJADI,Sodeh HEKMATSHOAR,Rahim OSKOOIE,Hossein A BAMOHARRAM,Fatemeh F 作者单位: HERAVI,Majid M.,SADJADI,Sodeh,HEKMATSHOAR,Rahim,OSKOOIE,Hossein A(Department of Chemistry,School of Sciences,Azzahra University,Vanak,Tehran,lran)BAMOHARRAM,Fatemeh F(Department of Chemistry,Islamic Azad University of Mashhad,Mashad,Iran)
刊 名: 中国化学(英文版) SCI 英文刊名: CHINESE JOURNAL OF CHEMISTRY 年,卷(期): 2009 27(3) 分类号: O6 关键词: oximes nitriles heteropolyacid green catalystchina