Thermal simulation of the formation and evolution of coalbed gas
Thermal simulation experiment of gas generation from the peat and the coals were performed using the high temperature and pressure apparatus, at temperature ranging from 336.8-600℃, a pressure of 50MPa and two heating rates of 20℃/h and 2℃/h, and the evolution and formation of coalbed gas components were studied. Results show that for the coals, the gaseous products are mainly composed of hydrocarbon gases. However, for the peat the content of hydrocarbon gases in gaseous products is lower than that of non-hydrocarbon components. In the generated hydrocarbon gases methane is predominant and heavy hydrocarbon gases (C2-5) are present in small amount.Meanwhile, carbon dioxide (CO2) predominates the generated non-hydrocarbon gases, and hydrogen (H2) and sulfurated hydrogen (H2S) are existent in trace amount. It is also observed that temperature is the main factor controlling the evolution of coalbed gas generation. With increasing vitrinite reflectance, methane rapidly increases, CO2 sightly increases, and C2-5 hydrocarbons first increase and then decrease. The peat and Shanxi formation coal have a higher generative potential of coalbed gases than coals and Taiyuan formation coal, respectively, reflecting the effect of the property of organic matter on the characteristics of coalbed gas component generation. In this study, it is found that low heating rate is favorable for the generation of methane, H2and CO2, and the decomposition of C2-5 hydrocarbons. This shows that heating time plays an important controlling role in the generation and evolution of coalbed gases. The results obtained from the simulation experiment in the study of coalbed gases in natural system are also discussed.
作 者： DUAN Yi WU Baoxiang ZHENG Chaoyang WANG Chuanyuan 作者单位： DUAN Yi(Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 730000, China)WU Baoxiang,ZHENG Chaoyang,WANG Chuanyuan(Key Laboratory of Gas Geochemistry, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 730000, China;Graduate School of Chinese Academy of Sciences, Beijing 100039, China)
刊 名： 科学通报（英文版） SCI 英文刊名： CHINESE SCIENCE BULLETIN 年，卷(期)： 2005 50(z1) 分类号： P61 关键词： coalbed gas generation and evolution pyrolysis peat coal heating rate