Reaction mechanism of 3-chlorophenol with OH, H in aqueous solution
The reaction mechanism of 3-chlorophenol with OH, H inaqueous solution was studied by transient technology. The3-chlorophenol aqueous solutions have been saturated with air or N2previously. Under alkaline condition, the reaction of OH radicalwith 3-chlorophenol produces 3-chlorinated phenoxyl radical, withthe absorption peaks at 400 nm and 417 nm. Under neutral condition,the reaction of OH radical with 3-chlorophenol produces OH-adductwith the maximal absorption at about 340 nm. And in acid solution,the reaction of H with 3-chlorophenol produces H-adduct with themaximal absorption at about 320 nm. 3-chlorophenol is compared with4- and 2-chlorophenols from the free radical pathways. The resultsshow that the positions of chlorine on the aromatic ring stronglyinfluence the dehalogenation and degradation process.
作 者： ZHU Jie CHEN Ye-fei DONG Wen-bo PAN Xun-xi HOU Hui-qi 作者单位： Institute of Environmental Science, Fudan University, Shanghai 200433, China 刊 名： 环境科学学报(英文版) ISTIC SCI 英文刊名： JOURNAL OF ENVIRONMENTAL SCIENCES 年，卷(期)： 2003 15(1) 分类号： X131.3 关键词： 3-chlorophenol OH radical atomic H microscopic