A New Three-dimensional Network Constructed by Heptamolybdate, Sodium Ions and Hexamethylene Tetramine Cations via Hydro
The crystal structure of the title compound [Na2(OH2)5]2+[C6H12N4H2]2-2+ [Mo7O24]6- · 4H2O, prepared from an aqueous solution of Na2MoO4·2H2O in the presence of MoCl3 and hexamethylene tetramine, has been determined by single-crystal X-ray diffraction. The crystal is of orthorhombic, space group Pnma with a = 14.6113(2), b = 18.6833(1), c = 15.3712(2)A, V = 4196.14(8)A3, Z = 4, Mr = 1548.13, F(000) = 3016, μ = 2.157 mm(1 and Dc = 2.451 g/cm3. The final R factor is 0.0526 for 3818 unique observed reflections (I > 2σ(I)). The structural analysis reveals that heptamolybdate anions in the title compound consist of seven edge-sharing MoO6 octahedra, and are linked into a three-dimensional framework by sodium ions and hydrogen bonds.
作 者： 杨文斌 卢灿忠 庄鸿辉 作者单位： State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China 刊 名： 结构化学 ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 年，卷(期)： 2002 21(2) 分类号： O64 关键词： heptamolybdate compound hydrogen bond three-dimensional network