Study on Synthesis and Intercalation Behavior of Layered Zirconium Proline-N-methylphosphonate-phosphate
Zirconium proline-N-methylphosphonate-phosphate (α-ZPMPP) was prepared in the presence of HF for the first time. The α-ZPMPP sample is highly crystallized with interlayer distance of 1.52 nm. The interlayer distance of complex of α-ZPMPP with n-butylamine (α-ZPMPP-BA) is in 0.45 nm larger than that of α-ZPMPP. The α-ZPMPP possesses different intercalation behavior of host-guest compound from α-ZP.
作 者: Xiao Ping RAO Xiang Kai FU Kai RAO 作者单位: College of Chemistry and Chemical Engineering,South-West China Normal University,Chongqing 400715 刊 名: 中国化学快报(英文版) ISTIC SCI 英文刊名: CHINESE CHEMICAL LETTERS 年,卷(期): 2004 15(7) 分类号: 关键词: Zirconium proline-N-methylphosphonate-phosphate n-butylamine intercalation complex interlayer distance host-guest compound