Promotion of the Direct Electron Transfer of Hemoglobin by the Carbon Nanotube
It is reported that the direct electron transfer of hemoglobin (Hb) can be effectively promoted by carbon nanotubes when Hb was immobilized on the surface of the carbon nanotubes modified electrode. The results indicated that the conversion of Hb-Fe(III)/Hb-Fe(II) is a one-electron coupled one-proton reaction process. The method presented can be easily extended to study the direct electrochemistry of other proteins or enzymes.
作 者: Jing CHEN Chen Xin CAI 作者单位: Department of Chemistry,Nanjing Normal University,Nanjing 210097 刊 名: 中国化学快报(英文版) ISTIC SCI 英文刊名: CHINESE CHEMICAL LETTERS 年,卷(期): 2004 15(7) 分类号: 关键词: Carbon nanotube direct electrochemistry modified electrode hemoglobin