氢氧混合体系下Ag/TS-1催化剂上丙烯的高效环氧化反应
Propylene oxide (PO) is one of the most important chemical feedstocks for producing polyether polyol polymers such as polyurethane. Commercially, PO is manufactured by either chlorohydrin or co-production (Halcon) route. The chlorohydrin route generates chlorinated by-products, mainly dichloropropane and CaCl2. The co-production route is capital intensive and its economics is linked to the economic fortunes of the by-products, namely styrene or tert-butyl alcohol.
作 者： 王瑞璞 郝敬泉 郭新闻 王祥生 作者单位： State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, Liaoning, China 刊 名： 催化学报 ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF CATALYSIS 年，卷(期)： 2003 24(5) 分类号： O643 关键词： silver TS-1 propylene epoxidation oxygen propylene oxide