Kinetic modelling of NO + CO reaction on Pt/MoOx /Al2O3 catalyst
A mathematical model has been developed to describe the dynamic behaviours of NO + CO reactionon supported Pt-MO-catalyst. The ignited state kinetics can be fitquantitatively using directly a Langmuir-Hens-helwood bimolecular rate expression with a heat of adsorption of NO of 32.4 kJ/mol and of CO of 106. 7 kJ/mol, respectively.
作 者： 焦宇兵 孙寿家 作者单位： Dept. of Environmental Science and Engineering, Harbin Institute of Technology, Harbin 150001, China 刊 名： 哈尔滨工业大学学报(英文版) EI 英文刊名： JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY(NEW SERIES) 年，卷(期)： 2003 10(2) 分类号： X169 关键词： modelling,mechanism NO CO platinum catalyst