Studies on Triterpenoids and Flavones in Glycyrrhiza uralensis Fisch. By HPLC-ESI-MSn and FT-ICR-MSn
Seven compounds, four flavones and three triterpenoids from Glycyrrhiza uralensis Fisch. Extract are identified by high performance liquid chromatography coupled with electrospray ionization multi-tandem mass spectrometry (HPLC-ESI-MSn). The fragmentation pathways of these compounds are investigated by ESI-MSn and Fourier transform ion cyclotron resonance multiple-stage tandem mass spectrometry (FT-ICR-MSn). Comparing the reten-tion times (tR) and mass spectra with those of reference compounds, seven components are identified in Glycyrrhiza uralensis Fisch. And their MSn data proposed plausible schemes for their fragmentation. All the experimental results show that ESI-MSn and FT-ICR-MSn are powerful tools for the structural characterization of triterpenoids and fla-vones.
作 者： MENG Xiangyu LI Huilin SONG Fengrui LIU Chunming LIU Zhiqiang LIU Shuying 作者单位： MENG Xiangyu,LI Huilin(Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun Center of Mass Spectrometry,Changchun,Jilin 130022,China;Graduate School of the Chinese Academy of Sciences,Beijing 100049,China)SONG Fengrui,LIU Chunming,LIU Zhiqiang,LIU Shuying(Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun Center of Mass Spectrometry,Changchun,Jilin 130022,China)
刊 名： 中国化学（英文版） SCI 英文刊名： CHINESE JOURNAL OF CHEMISTRY 年，卷(期)： 2009 27(2) 分类号： O6 关键词： Glycyrrhiza uralensis Fisch. triterpenoid flavone HPLC-ESI-MSn FT-ICR-MSn