丁二酮肟双核铜配合物的合成、结构和性能表征
The structure of [Cu2(Hdmg)4] (Hdmg = dimethylglyoxime anion) has been determined by X-ray crystallog-raphy. It is monoclinic, space group P21/n, with Z =2. The lattice parameters: a =0. 71601(14) nm; b =1.7044(3) nm; c=1.0126(4) nm; β=113.89(2)°; Mr=587.52 (C16H28Cu2N8O8); V=1.1299(5) nm3. Thecopper atom lies in a distorted square-pyramidal environment. The four equatorial donors are four nitrogen atomsfrom bidentate chelate dimethylglyoxime anion ligands. The oxygen atom from the dimethylglyoxime ligand acts as abridging atom occupying the apical position of the symmetry-related copper atom in the dimer structure. The twodimethylglyoximes bridge two copper atoms to form a six-member Cu2O2N2 ring, respectively. The thermal gravity(TG) data indicate that the compound [Cu2(Hdmg)4] undergoes two exothermic reactions with loss of the organicligand to give residue CuO. CCDC: 208729.
作 者： 建方方 孙萍萍 肖海连 作者单位： 青岛科技大学新材料与功能配合物实验室,青岛,266042 刊 名： 无机化学学报 ISTIC SCI PKU 英文刊名： CHINESE JOURNAL OF INORGANIC CHEMISTRY 年，卷(期)： 2003 19(7) 分类号： O618.121 关键词： 丁二酮肟 TG 双核铜 晶体结构 dimethylglyoxime TG dinuclear copper (Ⅱ) crystal structure