钟离君柏墓出土彩绘陶器颜料的光谱分析

钟离君柏墓出土彩绘陶器颜料的光谱分析

摘要：利用拉曼光谱结合X射线衍射物相检测方法,对安徽蚌埠双墩春秋中晚期钟离君柏墓出土彩绘陶器颜料的物相结构进行了分析测定.结果表明,陶器表面的红色、黄色和黑色颜料皆保存较好,未发生明显变化,分别是无机矿物朱砂(HgS)和针铁矿(α-FeO(OH))及炭黑.同时,拉曼光谱与X射线衍射分析的结果都显示红色颜料朱砂的组成物相单一,不含天然朱砂的伴生矿物石英,且其晶粒尺寸可能在纳米范围,应是由人工合成或经过古人的加工、纯化处理.针铁矿的发现表明春秋时期该矿物己被用作黄色颜料,这是目前己知的针铁矿作为黄颜料使用的最早的实例.Abstract：Based on the analysis of Raman spectroscopy and XRD methods, the structures of different pigments on the painted pottery from the Monarch Bai Tomb of Zhongli State in the middle and late Spring and Autumn period at Shungdun Village, Bengbu City, Anhui Province were analyzed. The result shows that all the pigments, including red, yellow and black pigments, have been well preserved, and these three pigments were identified as cinnabar, goethite and carbon black respectively. Both Raman spectroscopy and XRD analysis show that the crystal composition of red pigments, cinnabar, is very pure without quartz crystal, the associated crystal of natural cinnabar, and at the same time the crystal size of cinnabar is possibly at the nanometer scale It suggests that this red pigments perhaps were a synthetic material or processed and purified by our ancestors. The dis-covery of goethite shows that this mineral has been used as pigments as early as in the Spring and Autumn period. This is the earliest example that goethite was used as yellow pigments. 作者： 杨玉璋[1]  张居中[1]  左健[2]  阚绪杭[3]  周群[3] Author： YANG Yu-zhang[1]  ZHANG Ju-zhong[1]  ZUO Jian[2]  KAN Xu-hang[3]  ZHOU Qun[3] 作者单位： 中国科学技术大学科技史与科技考古系,安徽,合肥,230026中国科学技术大学合肥微尺度物质科学国家实验室(筹),安徽,合肥,230026安徽省文物考古研究所,安徽,合肥,230061 期 刊： 光谱学与光谱分析   ISTICEISCIPKU Journal： SPECTROSCOPY AND SPECTRAL ANALYSIS 年，卷(期)： 2010, 30(4) 分类号： P575.4 K876.3 关键词： 彩绘陶    颜料    拉曼光谱    X射线衍射    Keywords： Painted pottery    Pigments    Raman spectroscopy    XRD    机标分类号： TQ1 O41 机标关键词： 出土    彩绘    陶器颜料    光谱分析    Spring and Autumn period    Raman spectroscopy    针铁矿    射线衍射    拉曼光谱    analysis    nanometer scale    quartz crystal    black pigments    朱砂    物相    矿物    yellow    crystal size    carbon black    春秋中晚期 基金项目： 国家自然科学基金，中国科学院科研启动专项资金项目 钟离君柏墓出土彩绘陶器颜料的光谱分析[期刊论文]  光谱学与光谱分析 --2010, 30(4)杨玉璋  张居中  左健  阚绪杭  周群利用拉曼光谱结合X射线衍射物相检测方法,对安徽蚌埠双墩春秋中晚期钟离君柏墓出土彩绘陶器颜料的物相结构进行了分析测定.结果表明,陶器表面的红色、黄色和黑色颜料皆保存较好,未发生明显变化,分别是无机矿物朱砂(HgS...

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