[Ni(C6H4N2)(CHC6H4O)2]配合物晶体结构及性质
The complex has been synthesized and characterized by spectroscopic techniques and single-crystal X-rayanalysis. The crystal is orthorhombic , space group P212121 with a = 1. 6620(3) nm, b = 1. 7300(4) nm, c =0. 5450( 1 ) nm and Z = 4. In the crystal lattice, the molecules create a two-dimensional network structure throughmolecular plane structure perpendicular to the axis b, with the layers stacked by the Van der Waals interaction.
作 者: 王军 卑凤利 马卫兴 杨绪杰 陆路德 汪信 作者单位: 王军(南京理工大学材料化学实验室,南京,210094;江苏警官学院公安科技系,南京,210012)卑凤利,马卫兴,杨绪杰,陆路德,汪信(南京理工大学材料化学实验室,南京,210094)
刊 名: 无机化学学报 ISTIC SCI PKU 英文刊名: CHINESE JOURNAL OF INORGANIC CHEMISTRY 年,卷(期): 2003 19(6) 分类号: O614.81 关键词: 镍配合物 水杨醛 邻苯二胺 晶体结构 席夫碱 nickel (Ⅱ) complex salicylaldehyde o-phenylenediamine crystal structure Schiff base