Transformation of Oximes and Alcohols to Carbonyl Compounds Using Amberlite IRA-400 Supported Chromic Acid in the Presen
A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ketones in good to excellent yields using amberlite IRA-400 supported chromic acid in the presence of zirconium tetrachlo-ride in refluxing acetonitrile-H2O. Selective oxidation of oximes and alcohols in the presence of other functional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method. A wide variety of oximes and alcohols were efficiently converted to their corresponding aldehydes and ke-tones in good to excellent yields using amberlite IRA-400 supported chromic acid in the presence of zirconium tet-rachloride in refluxing acetonitrile-H2O. Selective oxidation of oximes and alcohols in the presence of other func-tional groups such as acetal, hydrazone, aldehyde, ether and alkene can be considered as a noteworthy advantage of this method.
作 者： BAHRAMI, Kiumars KHODAEIMohammad-Mehdi GORGIN-KARAJI, Usef 作者单位： Department of Chemistry,Razi University,Kermanshah 67149,Iran Nanoscience and Nanotechnology Research Center (NNRC),Razi University,Kermanshah 67149,Iran 刊 名： 中国化学（英文版） SCI 英文刊名： CHINESE JOURNAL OF CHEMISTRY 年，卷(期)： 2009 27(2) 分类号： O6 关键词： oxidation amberlite IRA-400 oxime alcohol